Nuclear fusion
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In physics and nuclear chemistry, nuclear fusion is the process by which multiple atomic particles join together to form a heavier nucleus. It is accompanied by the release or absorption of energy. Iron and nickel nuclei have the largest binding energies per nucleon of all nuclei. The fusion of two nuclei lighter than iron generally releases energy while the fusion of nuclei heavier than iron absorbs energy; vice-versa for the reverse process, nuclear fission.
Nuclear fusion occurs naturally in stars. Artificial fusion in human enterprises has also been achieved, although not yet completely controlled. Building upon the nuclear transmutation experiments of Ernest Rutherford done a few years earlier, fusion of light nuclei (hydrogen isotopes) was first observed by Mark Oliphant in 1932, and the steps of the main cycle of nuclear fusion in stars were subsequently worked out by Hans Bethe throughout the remainder of that decade. Research into fusion for military purposes began in the early 1940s, as part of the Manhattan Project, but was not successful until 1952. Research into controlled fusion for civilian purposes began in the 1950s, and continues to this day.
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[ Overview
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Fusion reactions power the stars and produce all but the lightest elements in a process called nucleosynthesis. While the fusion of lighter elements in stars releases energy, production of the heavier elements absorbs energy.
When the fusion reaction is a sustained uncontrolled chain, it can result in a thermonuclear explosion, such as that generated by a hydrogen bomb. Reactions which are not self-sustaining can still release considerable energy, as well as large numbers of neutrons.
Research into controlled fusion, with the aim of producing fusion power for the production of electricity, has been conducted for over 50 years. It has been accompanied by extreme scientific and technological difficulties, but resulted in steady progress. As of the present, break-even (self-sustaining) controlled fusion reaction have been demonstrated in a few tokamak-type reactors around the world and resulted in producing workable design of the reactor which will deliver ten times more fusion energy than the amount of energy needed to heat up its plasma to required temperatures (see ITER which is scheduled to be operational in 2016).
It takes considerable energy to force nuclei to fuse, even those of the lightest element, hydrogen. This is because all nuclei have a positive charge (due to their protons), and as like charges repel, nuclei strongly resist being put too close together. Accelerated to high speeds (that is, heated to thermonuclear temperatures), they can overcome this electromagnetic repulsion and get close enough for the attractive nuclear force to be sufficiently strong to achieve fusion. The fusion of lighter nuclei, creating a heavier nucleus and a free neutron, will generally release more energy than it took to force them together-an exothermic process that can produce self-sustaining reactions.
The energy released in most nuclear reactions is much larger than that in chemical reactions, because the binding energy that holds a nucleus together is far greater than the energy that holds electrons to a nucleus. For example, the ionization energy gained by adding an electron to a hydrogen nucleus is 13.6 electron volts - less than one-millionth of the 17 MeV released in the D-T (deuterium-tritium) reaction shown to the top right. Fusion reactions have an energy density many times greater than nuclear fission-that is, per unit of mass the reactions produce far greater energies, even though individual fission reactions are generally much more energetic than individual fusion reactions-which are themselves millions of times more energetic than chemical reactions. Only the direct conversion of mass into energy, such as with collision of matter and antimatter, is more energetic per unit of mass than nuclear fusion.
[ Requirements
A substantial energy barrier must be overcome before fusion can occur. At large distances two naked nuclei repel one another because of the repulsive electrostatic force between their positively charged protons. If two nuclei can be brought close enough together, however, the electrostatic repulsion can be overcome by the attractive nuclear force which is stronger at close distances.
When a nucleon such as a proton or neutron is added to a nucleus, the nuclear force attracts it to other nucleons, but primarily to its immediate neighbors due to the short range of the force. The nucleons in the interior of a nucleus have more neighboring nucleons than those on the surface. Since smaller nuclei have a larger surface area-to-volume ratio, the binding energy per nucleon due to the strong force generally increases with the size of the nucleus but approaches a limiting value corresponding to that of a fully surrounded nucleon.
The electrostatic force, on the other hand, is an inverse-square force, so a proton added to a nucleus will feel an electrostatic repulsion from all the other protons in the nucleus. The electrostatic energy per nucleon due to the electrostatic force thus increases without limit as nuclei get larger.
The net result of these opposing forces is that the binding energy per nucleon generally increases with increasing size, up to the elements iron and nickel, and then decreases for heavier nuclei. Eventually, the binding energy becomes negative and very heavy nuclei are not stable. The four most tightly bound nuclei, in decreasing order of binding energy, are 62Ni, 58Fe, 56Fe, and 60Ni.[1] Even though the nickel isotope ,62Ni, is more stable, the iron isotope 56Fe is an order of magnitude more common. This is due to a greater disintegration rate for 62Ni in the interior of stars driven by photon absorption.
A notable exception to this general trend is the helium-4 nucleus, whose binding energy is higher than that of lithium, the next heavier element. The Pauli exclusion principle provides an explanation for this exceptional behavior—it says that because protons and neutrons are fermions, they cannot exist in exactly the same state. Each proton or neutron energy state in a nucleus can accommodate both a spin up particle and a spin down particle. Helium-4 has an anomalously large binding energy because its nucleus consists of two protons and two neutrons; so all four of its nucleons can be in the ground state. Any additional nucleons would have to go into higher energy states.
The situation is similar if two nuclei are brought together. As they approach each other, all the protons in one nucleus repel all the protons in the other. Not until the two nuclei actually come in contact can the strong nuclear force take over. Consequently, even when the final energy state is lower, there is a large energy barrier that must first be overcome. It is called the Coulomb barrier.
The Coulomb barrier is smallest for isotopes of hydrogen—they contain only a single positive charge in the nucleus. A bi-proton is not stable, so neutrons must also be involved, ideally in such a way that a helium nucleus, with its extremely tight binding, is one of the products.
Using deuterium-tritium fuel, the resulting energy barrier is about 0.01 MeV.[citation needed] In comparison, the energy needed to remove an electron from hydrogen is 13.6 eV, about 750 times less energy. The (intermediate) result of the fusion is an unstable 5He nucleus, which immediately ejects a neutron with 14.1 MeV.[citation needed] The recoil energy of the remaining 4He nucleus is 3.5 MeV,[citation needed] so the total energy liberated is 17.6 MeV.[citation needed] This is many times more than what was needed to overcome the energy barrier.
If the energy to initiate the reaction comes from accelerating one of the nuclei, the process is called beam-target fusion; if both nuclei are accelerated, it is beam-beam fusion. If the nuclei are part of a plasma near thermal equilibrium, one speaks of thermonuclear fusion. Temperature is a measure of the average kinetic energy of particles, so by heating the nuclei they will gain energy and eventually have enough to overcome this 0.01 MeV. Converting the units between electronvolts and kelvins shows that the barrier would be overcome at a temperature in excess of 120 million kelvins, obviously a very high temperature.
There are two effects that lower the actual temperature needed. One is the fact that temperature is the average kinetic energy, implying that some nuclei at this temperature would actually have much higher energy than 0.01 MeV, while others would be much lower. It is the nuclei in the high-energy tail of the velocity distribution that account for most of the fusion reactions. The other effect is quantum tunneling. The nuclei do not actually have to have enough energy to overcome the Coulomb barrier completely. If they have nearly enough energy, they can tunnel through the remaining barrier. For this reason fuel at lower temperatures will still undergo fusion events, at a lower rate.
The reaction cross section σ is a measure of the probability of a fusion reaction as a function of the relative velocity of the two reactant nuclei. If the reactants have a distribution of velocities, e.g. a thermal distribution with thermonuclear fusion, then it is useful to perform an average over the distributions of the product of cross section and velocity. The reaction rate (fusions per volume per time) is <σv> times the product of the reactant number densities:
If a species of nuclei is reacting with itself, such as the DD reaction, then the product n1n2 must be replaced by (1 / 2)n2.
increases from virtually zero at room temperatures up to meaningful magnitudes at temperatures of 10 – 100 keV. At these temperatures, well above typical ionization energies (13.6 eV in the hydrogen case), the fusion reactants exist in a plasma state.
The significance of <σv> as a function of temperature in a device with a particular energy confinement time is found by considering the Lawson criterion.
[ Gravitational confinement
One force capable of confining the fuel well enough to satisfy the Lawson criterion is gravity. The mass needed, however, is so great that gravitational confinement is only found in stars (the smallest of which are brown dwarfs). Even if the more reactive fuel deuterium were used, a mass greater than that of the planet Jupiter would be needed.
[ Magnetic confinement
- See Magnetic confinement fusion for more information.
The charged ions of fusion fuel follow spiral orbits around magnetic field lines (see Guiding center#Gyration), and the fuel is therefore trapped along the field lines. A variety of magnetic configurations exist, including the toroidal geometries of tokamaks and stellarators and open ended mirror confinement systems.
[ Inertial confinement
- See Inertial fusion energy for more information.
A third confinement principle is to apply a rapid pulse of energy to a large part of the surface of a pellet of fusion fuel, causing it to simultaneously "implode" and heat to very high pressure and temperature. If the fuel is dense enough and hot enough, the fusion reaction rate will be high enough to burn a significant fraction of the fuel before it has dissipated. To achieve these extreme conditions, the initially cold fuel must be explosively compressed. Inertial confinement is used in the hydrogen bomb, where the driver is x-rays created by a fission bomb. Inertial confinement is also attempted in "controlled" nuclear fusion, where the driver is a laser, ion, or electron beam, or a Z-pinch.
Some confinement principles have been investigated, such as muon-catalyzed fusion, the Farnsworth-Hirsch fusor and Polywell (inertial electrostatic confinement), and bubble fusion.
[ Production methods
A variety of methods are known to affect nuclear fusion. Some are "cold" in the strict sense that no part of the material is hot (except for the reaction products), some are "cold" in the limited sense that the bulk of the material is at a relatively low temperature and pressure but the reactants are not, and some are "hot" fusion methods that create macroscopic regions of very high temperature and pressure.
[ Locally cold fusion
- Muon-catalyzed fusion is a well-established and reproducible fusion process that occurs at ordinary temperatures. It was studied in detail by Steven Jones in the early 1980s. It has not been reported to produce net energy. Net energy production from this reaction is not believed to be possible because of the energy required to create muons, their 2.2 µs half-life, and the chance that a muon will bind to the new alpha particle and thus stop catalyzing fusion.
- "Cold fusion" also refers to a simple method using electrodes (generally palladium) in heavy water, which many claim has not been verified to be possible. Anomalous excess heat and residual traces of Tritium and Helium in the deuterated electrolyte, have been reported in numerous replicated[citation needed] experiments, but peer consensus is still divided.
[ Generally cold, locally hot fusion
- Accelerator based light-ion fusion. Using particle accelerators it is possible to achieve particle kinetic energies sufficient to induce many light ion fusion reactions. Accelerating light ions is relatively easy, cheap, and can be done in an efficient manner - all it takes is a vacuum tube, a pair of electrodes, and a high-voltage transformer; fusion can be observed with as little as 10 kilovolt between electrodes. The key problem with accelerator-based fusion (and with cold targets in general) is that fusion cross sections are many orders of magnitude lower than Coulomb interaction cross sections. Therefore vast majority of ions ends up expending their energy on bremsstrahlung and ionization of atoms of the target. Devices referred to as sealed-tube neutron generators are particularly relevant to this discussion. These small devices are miniature particle accelerators filled with deuterium and tritium gas in an arrangement which allows ions of these nuclei to be accelerated against hydride targets, also containing deuterium and tritium, where fusion takes place. Hundreds of neutron generators are produced annually for use in the petroleum industry where they are used in measurement equipment for locating and mapping oil reserves. Despite periodic reports in the popular press by scientists claiming to have invented "table-top" fusion machines, neutron generators have been around for half a century. The sizes of these devices vary but the smallest instruments are often packaged in sizes smaller than a loaf of bread. These devices do not produce a net power output.
- In sonoluminescence, acoustic shock waves create temporary bubbles that collapse shortly after creation, producing very high temperatures and pressures. In 2002, Rusi P. Taleyarkhan reported the possibility that bubble fusion occurs in those collapsing bubbles (aka sonofusion). As of 2005, experiments to determine whether fusion is occurring give conflicting results. If fusion is occurring, it is because the local temperature and pressure are sufficiently high to produce hot fusion.[2] In an episode of Horizon, on BBC television, results were presented showing that, although temperatures were reached which could initiate fusion on a large scale, no fusion was occurring, and inaccuracies in the measuring system were the cause of anomalous results.
- The Farnsworth-Hirsch Fusor is a tabletop device in which fusion occurs. This fusion comes from high effective temperatures produced by electrostatic acceleration of ions. The device can be built inexpensively, but it too is unable to produce a net power output.
- Antimatter-initialized fusion uses small amounts of antimatter to trigger a tiny fusion explosion. This has been studied primarily in the context of making nuclear pulse propulsion feasible. This is not near becoming a practical power source, due to the cost of manufacturing antimatter alone.
- Pyroelectric fusion was reported in April 2005 by a team at UCLA. The scientists used a pyroelectric crystal heated from −34 to 7°C (−30 to 45°F), combined with a tungsten needle to produce an electric field of about 25 gigavolts per meter to ionize and accelerate deuterium nuclei into an erbium deuteride target. Though the energy of the deuterium ions generated by the crystal has not been directly measured, the authors used 100 keV (a temperature of about 109 K) as an estimate in their modeling.[3] At these energy levels, two deuterium nuclei can fuse together to produce a helium-3 nucleus, a 2.45 MeV neutron and bremsstrahlung. Although it makes a useful neutron generator, the apparatus is not intended for power generation since it requires far more energy than it produces.[4][5][6][7]
[ Hot fusion
In "standard" "hot" fusion, the fuel reaches tremendous temperature and pressure inside a fusion reactor or nuclear weapon.
The methods in the second group are examples of non-equilibrium systems, in which very high temperatures and pressures are produced in a relatively small region adjacent to material of much lower temperature. In his doctoral thesis for MIT, Todd Rider did a theoretical study of all quasineutral, isotropic, non-equilibrium fusion systems. He demonstrated that all such systems will leak energy at a rapid rate due to bremsstrahlung radiation produced when electrons in the plasma hit other electrons or ions at a cooler temperature and suddenly decelerate. The problem is not as pronounced in a hot plasma because the range of temperatures, and thus the magnitude of the deceleration, is much lower. Note that Rider's work does not apply to non-neutral and/or anisotropic non-equilibrium plasmas.
[ Important reactions
[ Astrophysical reaction chains
The most important fusion process in nature is that which powers the stars. The net result is the fusion of four protons into one alpha particle, with the release of two positrons, two neutrinos (which changes two of the protons into neutrons), and energy, but several individual reactions are involved, depending on the mass of the star. For stars the size of the sun or smaller, the proton-proton chain dominates. In heavier stars, the CNO cycle is more important. Both types of processes are responsible for the creation of new elements as part of stellar nucleosynthesis.
At the temperatures and densities in stellar cores the rates of fusion reactions are notoriously slow. For example, at solar core temperature (T ≈ 15 MK) and density (160 g/cm³), the energy release rate is only 276 μW/cm³—about a quarter of the volumetric rate at which a resting human body generates heat. [8] Thus, reproduction of stellar core conditions in a lab for nuclear fusion power production is completely impractical. Because nuclear reaction rates strongly depend on temperature (exp(−E/kT)), then in order to achieve reasonable rates of energy production in terrestrial fusion reactors 10–100 times higher temperatures (compared to stellar interiors) are required T ≈ 0.1–1.0 GK.
[ Criteria and candidates for terrestrial reactions
In man-made fusion, the primary fuel is not constrained to be protons and higher temperatures can be used, so reactions with larger cross-sections are chosen. This implies a lower Lawson criterion, and therefore less startup effort. Another concern is the production of neutrons, which activate the reactor structure radiologically, but also have the advantages of allowing volumetric extraction of the fusion energy and tritium breeding. Reactions that release no neutrons are referred to as aneutronic.
In order to be useful as a source of energy, a fusion reaction must satisfy several criteria. It must
- be exothermic: This may be obvious, but it limits the reactants to the low Z (number of protons) side of the curve of binding energy. It also makes helium 4He the most common product because of its extraordinarily tight binding, although 3He and 3H also show up;
- involve low Z nuclei: This is because the electrostatic repulsion must be overcome before the nuclei are close enough to fuse;
- have two reactants: At anything less than stellar densities, three body collisions are too improbable. It should be noted that in inertial confinement, both stellar densities and temperatures are exceeded to compensate for the shortcomings of the third parameter of the Lawson criterion, ICF's very short confinement time;
- have two or more products: This allows simultaneous conservation of energy and momentum without relying on the electromagnetic force;
- conserve both protons and neutrons: The cross sections for the weak interaction are too small.
Few reactions meet these criteria. The following are those with thee largest cross sections:
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(1) 21D + 31T → 42He ( 3.5 MeV ) + n0 ( 14.1 MeV ) (2i) 21D + 21D → 31T ( 1.01 MeV ) + p+ ( 3.02 MeV ) 50% (2ii) → 32He ( 0.82 MeV ) + n0 ( 2.45 MeV ) 50% (3) 21D + 32He → 42He ( 3.6 MeV ) + p+ ( 14.7 MeV ) (4) 31T + 31T → 42He + 2 n0 + 11.3 MeV (5) 32He + 32He → 42He + 2 p+ + 12.9 MeV (6i) 32He + 31T → GFDL.
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